Second-sphere coordination of ‘star’-shaped hexakis(N-pyridin-4-one)benzene (HPOB) with hexakis(methanol)nickel(II) nitrate; unusual (NO3−)(HPOB)(NO3−) π-stacked ‘sandwiching’

Autor:	David A. Grachvogel, David J. Williams, David M. L. Goodgame
Rok vydání:	2002
Předmět:	Nickel(II) nitrate Hydrogen bond Crystal structure Ring (chemistry) Photochemistry Inorganic Chemistry Metal chemistry.chemical_compound Crystallography chemistry visual_art Materials Chemistry visual_art.visual_art_medium Molecule Methanol Physical and Theoretical Chemistry Benzene
Zdroj:	Inorganica Chimica Acta. 330:13-16
ISSN:	0020-1693
DOI:	10.1016/s0020-1693(01)00702-2
Popis:	It is shown by X-ray studies that the compound Ni(HPOB)(NO3)2(MeOH)9 [where HPOB=hexaxis(N-pyridin-4-one)benzene] contains [Ni(MeOH)6]2+ cations hydrogen-bonded to the oxygen atoms of the pyridone units in HPOB, with the resulting six-connectivity at both metal and HPOB producing a three-dimensional network array essentially topologically equivalent to the α-Po structure. The pyridone rings in the HPOB molecules are arranged orthogonally to the central C6 ring and the nitrate anions form an unusual (NO3 −)(HPOB)(NO3 −) ‘sandwich’ by a combination of π-stacking and CH⋯O hydrogen bonds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1c91145c260ce8956db38de587705f7b https://doi.org/10.1016/s0020-1693(01)00702-2 Zobrazit plný text záznamu Full Text from ScienceDirect