Reactivity of vinyl chloride ionic clusters

Autor:	Christophe Jouvet, C. Dedonder-Lardeux, I. Dimicoli, D. Solgadi, Gilles Grégoire, Michel Mons, S. Martrenchard
Rok vydání:	1998
Předmět:	Ionic clusters Dimer Inorganic chemistry Evaporation General Physics and Astronomy Trimer Photochemistry Vinyl chloride chemistry.chemical_compound Elimination reaction Monomer chemistry Reactivity (chemistry) Physical and Theoretical Chemistry
Zdroj:	Chemical Physics. 239:331-343
ISSN:	0301-0104
DOI:	10.1016/s0301-0104(98)00255-9
Popis:	The reactivity of vinyl chloride ionic clusters has been investigated by the Threshold PhotoElectron PhotoIon COincidences technique. In the case of the dimer, the competition between the three reactive channels (HCl, Cl ⋅ and CH 2 Cl elimination) has been studied. The main reactive channel is HCl elimination which proceeds through a 0.2 eV barrier. This elimination reaction is still observed in the trimer but not in larger clusters. For these clusters, cooling by evaporation of neutral vinyl chloride monomers seems to be the favored channel that hinders the HCl elimination step.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1c4db227f846e34f75fb03064750191f https://doi.org/10.1016/s0301-0104(98)00255-9 Zobrazit plný text záznamu Full Text from ScienceDirect