A New Metalloligand Powerful in Forming Helical Coordination Polymers
| Autor: | Yan-Long Lan, P. P. Hao, S. Z. Zhang, Li-Na Zhu, B. Yuan, Xiao-Zeng Li |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis 010405 organic chemistry General Chemical Engineering Infrared spectroscopy General Chemistry Polymer 010402 general chemistry 01 natural sciences 0104 chemical sciences Metal Crystallography chemistry.chemical_compound Heteronuclear molecule chemistry visual_art visual_art.visual_art_medium Thermal stability Carboxylate Single crystal |
| Zdroj: | Russian Journal of Coordination Chemistry. 43:700-707 |
| ISSN: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328417100116 |
| Popis: | A new macrocyclic oxamido carboxylate metalloligand was designed and three heteronuclear coordination polymers of the metalloligand and metal nodes Cu2+, Zn2+ and Cd2+ were prepared. X-ray single crystal analyses (CIF files CCDC nos. 1025722–1025724 for I–III) revealed that multiple favourable features endowed the metalloligand with a strong power to force the metal nodes to generate 1D helical coordination polymers. Thermogravimetric analyses showed that the complexes with Cu2+ and Zn2+ nodes exhibited moderate thermal stability. The three complexes were also characterized by IR spectra and PXRD. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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