Relative stereochemistries of the ether rings and sugar moieties in durinskiol A

Autor:	Takeshi Iwashita, Tomoyuki Koyama, Atsushi Wakamiya, Kaoru Yamada, Daisuke Uemura, Eric R.O. Siwu, Takahiro Takiguchi, Masaki Kita, Michael C. Roy, Isao Noma
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Molecular model Chemistry Stereochemistry Organic Chemistry Ab initio Glycoside Ether Ring (chemistry) Biochemistry chemistry.chemical_compound Polyol Computational chemistry Drug Discovery Sugar
Zdroj:	Tetrahedron Letters. 48:3429-3432
ISSN:	0040-4039
Popis:	Durinskiol A (1) is a long carbon-chain polyol compound with a molecular weight of 2128 mu isolated from the symbiotic dinoflagellate Durinskia sp. The relative stereochemistries of ether rings and sugar moieties in 1 were established based on 2D-NMR analysis and molecular modeling studies. Conformational analysis of the 6,5,6-bis-spiroacetal ring in 1 was also examined by using ab initio methods.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1c16b695c27dda0213456349ce4dd739 https://doi.org/10.1016/j.tetlet.2007.03.039 Zobrazit plný text záznamu Full Text from ScienceDirect