(1RS,3SR,4RS,5RS,7SR,9SR)-4,7-Diacetyl-9-hydroxy-1,3,5,9-tetramethyl-2,6,8-trioxatricyclo[3.2.1.13,7]nonane: a Tricyclic System Formed Under Cathodic Conditions

Autor: Sydney Hall, J. Simons, G. Raabe, Hans Günter Thomas, U. Wellen
Rok vydání: 1997
Předmět:
Zdroj: Acta Crystallographica Section C Crystal Structure Communications. 53:1107-1111
ISSN: 0108-2701
DOI: 10.1107/s0108270197005477
Popis: The title compound, C14H20O6, generated from a bicyclic precursor under electrochemical conditions, crystallizes with six identical molecules in the asymmetric unit. Comparison of equivalent bond lengths and angles reveals no major structural differences between the molecules. However, the intermolecular distances suggest that the molecular packing is due to pairwise attractive interactions between the species, resulting in three different types of dimers. The crystal lattice can be described as a layer structure with strata either perpendicular or parallel to the ac plane.
Databáze: OpenAIRE