Metal Cluster Catalysis: A Kinetic and Mechanistic Study of the Carbonylation of Methanol to Give Methyl Formate as Catalyzed by [Et4N]2[Fe3(CO)9E] (E = S, Se, Te)

Autor:	Jaap W. van Hal, Ilse Y. Guzman-Jimenez, Kenton H. Whitmire
Rok vydání:	2003
Předmět:	Methyl formate Organic Chemistry Kinetic energy Medicinal chemistry Catalysis Inorganic Chemistry Metal chemistry.chemical_compound chemistry Homogeneous visual_art Cluster (physics) visual_art.visual_art_medium Organic chemistry Methanol Physical and Theoretical Chemistry Carbonylation
Zdroj:	Organometallics. 22:1914-1922
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om020548+
Popis:	The cluster compounds [Et4N]2[Fe3(CO)9E] (E = S, Se, Te) catalyze the homogeneous carbonylation of methanol to form methyl formate under moderate CO pressures (600−1200 psi) between 50 and 90 °C. A...
Databáze:	OpenAIRE
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