Simultaneous catalytic H2 production and CO2 capture in steam reforming of toluene as tar model compound from biomass gasification

Autor: Claire Courson, I. Zamboni, Daniel Niznansky, Alain Kiennemann
Rok vydání: 2014
Předmět:
Zdroj: Applied Catalysis B: Environmental. 145:63-72
ISSN: 0926-3373
DOI: 10.1016/j.apcatb.2013.02.046
Popis: During biomass gasification in a fast internal circulating fluidized bed (FICFB) reactor hydrogen production is strongly influenced by the physicochemical properties and ability of the catalyst to transform the organic fraction (tar molecules), considered as pollutant and produced along the process. The hydrogen production can be also favored by the sorption of CO 2 formed during biomass gasification. In this work, two types of bi-functional sorbents/catalysts were prepared taking into account the high attrition resistance required in this type of reactor. Olivine was chosen as catalyst and support of CaO or CaO–Ca 12 Al 14 O 33 (CaO–CaAl) used as CO 2 sorbent phases. The bi-functional materials and olivine were characterized by SEM, BET, XRD, TPR and Mossbauer spectroscopy. The SEM and BET analyses showed that the higher content of CaO–CaAl on olivine allowed having larger pore volume and smaller pore size than CaO/olivine. XRD and TPR showed that the formation of α-Fe 2 O 3 by oxidation of Fe 2+ from the olivine structure is favored in presence of the CaO–Ca 12 Al 14 O 33 phase which improves iron oxide dispersion. The CaO–CaAl/olivine 1:2 ratio showed the best sorption properties at 700 °C. The CO 2 sorption capacity was attributed to the high CaO content and its large pore volume while the presence of Ca 12 Al 14 O 33 provided CO 2 sorption stability during carbonation–decarbonation cycles. The enhancement of catalytic activity in tar conversion for these bi-functional materials compared to olivine was demonstrated and attributed to the presence of well dispersed iron oxides and the high content of sorbent on olivine surface. This work presents the interest of a CaO–CaAl/olivine catalyst for hydrogen production improved by CO 2 capture in a fast internal circulating fluidized bed biomass gasifier.
Databáze: OpenAIRE
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