Sila-rhubafuran and Derivatives: Synthesis and Olfactory Characterization of Novel Silicon-Containing Odorants

Autor:	Rüdiger Bertermann, Bettina Förster, Reinhold Tacke, Philip Kraft
Rok vydání:	2013
Předmět:	Inorganic Chemistry Silicon chemistry Stereochemistry Organic Chemistry Domain (ring theory) Diastereomer Organic chemistry chemistry.chemical_element Physical and Theoretical Chemistry Characterization (materials science)
Zdroj:	Organometallics. 33:338-346
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om401070c
Popis:	Sila-rhubafuran (1b), a silicon analogue of the grapefruit odorant rhubafuran (1a), was synthesized and isolated as a 1:1 mixture of two racemic diastereomers. In addition, the structurally related racemic C/Si pairs 2a/2b and 3a/3b were prepared. To get information about structure–odor relationships in the domain of grapefruit odorants, the C/Si pairs 1a/1b, 2a/2b, and 3a/3b were studied for their olfactory properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1ba797f9dcab20f7fbb00c4c790fbc67 https://doi.org/10.1021/om401070c Zobrazit plný text záznamu