Model filled polymers. XI. Synthesis of monodisperse crosslinked polymethacrylonitrile beads
| Autor: | D. Zou, J. J. Aklonis, Ronald Salovey |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Nitrile Organic Chemistry Dispersity technology industry and agriculture Emulsion polymerization macromolecular substances Polymer chemistry.chemical_compound chemistry Polymerization Methacrylonitrile Polymer chemistry Materials Chemistry Particle size Emulsion copolymerization |
| Zdroj: | Journal of Polymer Science Part A: Polymer Chemistry. 30:2443-2449 |
| ISSN: | 1099-0518 0887-624X |
| DOI: | 10.1002/pola.1992.080301118 |
| Popis: | Monodisperse polymethacrylonitrile beads of varied size and crosslink density are prepared by emulsion copolymerization of methacrylonitrile and allylmethacrylate in the absence of emulsifier. The particle size is very sensitive to polymerization temperature and initiator concentration. Because of a nitrile group effect, the maximum conversion varies with reaction conditions. The highest conversion obtained was 82%. © 1992 John Wiley & Sons, Inc. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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