Biotransformation of (±)-Lavandulol by the Plant Pathogenic Fungus Glomerella cingulata

Autor:	Hiromu Kameoka, Mitsuo Miyazawa, Shin-ichi Akazawa, Hirokazu Nankai
Rok vydání:	1998
Předmět:	biology Stereochemistry General Chemistry Tetrahydropyran Carbon-13 NMR Pathogenic fungus biology.organism_classification Glomerella cingulata Terpenoid chemistry.chemical_compound Metabolic pathway Biochemistry Biotransformation chemistry General Agricultural and Biological Sciences Lavandulol
Zdroj:	Journal of Agricultural and Food Chemistry. 46:3858-3862
ISSN:	1520-5118 0021-8561
Popis:	To clarify the structures of biotransformation products and the metabolic pathways, the microbial transformation of (±)-lavandulol has been investigated using the plant pathogenic fungus Glomerella cingulata. (±)-Lavandulol [(±)-5-methyl-2-(1-methylethenyl)-4-hexen-1-ol] was mainly oxidized at the C-4 double bond to give (−)-(2S,4S)-1,5-epoxy-5-methyl-2-(1-methylethenyl)-4-hexanol and cis- and trans-1,4-epoxy-5-methyl-2-(1-methylethenyl)-5-hexanol. 5-Methyl-2-(1-methylethenyl)-4-hexene-1,6-diol (6-hydroxylavandulol) was also produced through this biotransformation. These structures were confirmed by the mass, IR, 1H NMR, and 13C NMR spectral data. Keywords: Biotransformation; microbial transformation; Glomerella cingulata; plant pathogenic fungus; (±)-lavandulol; tetrahydropyran; tetrahydrofuran
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1b67f1a6e63b1577b9fa802734e18f67 https://doi.org/10.1021/jf970696o Zobrazit plný text záznamu