Mechanisms and stereochemistry of amine substitution reactions at the carbon-nitrogen double bond

Autor:	Susan L. Todd, Reidun M. Alderman, James E. Johnson, Martha Hotema, Susan M. Dutson, Abdolkarim Ghafouripour
Rok vydání:	1992
Předmět:	Substitution reaction chemistry.chemical_classification chemistry.chemical_compound Reaction mechanism chemistry Double bond Stereochemistry Morpholine Organic Chemistry Azetidine Amine gas treating Piperidine Pyrrolidine
Zdroj:	The Journal of Organic Chemistry. 57:4648-4653
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo00043a022
Popis:	The reaction of (Z)-O-methyl-nitrobenzohydroximoyl chloride [4-NO 2 C 6 H 4 C(CI)=NOCH 3 ] with morpholine, piperidine, pyrrolidine, and azetidine gives the corresponding (Z)-amidoximes (4-NO 2 C 6 H 4 C(NR 1 R 2 )=NOCH 3 ]. The rate equations for these reactions in benzene solution contain both first-order and second-order terms in amine
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1b671499d40ed289f19a1f92222bb58d https://doi.org/10.1021/jo00043a022 Zobrazit plný text záznamu