Sequence of alkylation of cyclohexane-1, 3-dione. Alternative synthesis of (±)-Angustione

Autor:	L. I. Ukhova, L. G. Lis, A. A. Zenyuk
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Cyclohexane Stereochemistry Diisopropylamine Sequence (biology) Plant Science General Chemistry Alkylation General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound chemistry Acetyl chloride Molecule Alkyl Methyl iodide
Zdroj:	Chemistry of Natural Compounds. 27:400-403
ISSN:	1573-8388 0009-3130
DOI:	10.1007/bf00636555
Popis:	A method is proposed for introducing one, two, or three alkyl substituents into positions 4 and 6 of the cyclohexane-1, 3-dione molecule by successive alkylation under the action of strong bases. (±)-Angustione (a natural β-diketone) has been synthesized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1b6189c741c57964170dfc118677b656 https://doi.org/10.1007/bf00636555 Zobrazit plný text záznamu Full text from SpringerLink