Accelerating rate calorimetry study on the thermal stability of interpenetrating network type poly(siloxane-g-ethylene oxide) polymer electrolyte

Autor:	Khalil Amine, Bookeun Oh, Yoo-Eup Hyung, Donald R. Vissers
Rok vydání:	2003
Předmět:	Exothermic reaction Materials science Ethylene oxide General Chemical Engineering Electrolyte chemistry.chemical_compound Chemical engineering chemistry Siloxane Heat generation Polymer chemistry Electrochemistry Thermal stability Interpenetrating polymer network Ethylene carbonate
Zdroj:	Electrochimica Acta. 48:2215-2220
ISSN:	0013-4686
DOI:	10.1016/s0013-4686(03)00207-x
Popis:	Safety study regarding an exothermic reaction at elevated temperature of comb-shaped siloxane polymer and its interpenetrating network type solid polymer electrolyte (SPE) are investigated. Accelerating rate calorimetry (ARC) is used to examine exothermic reactions. The thermal stability of the polymer electrolyte in the presence of charged electrodes is also monitored. Resulting data were compared with those of 1.0 M LiPF 6 in ethylene carbonate:ethyl methyl carbonate (3:7 by wt.) electrolyte. The self-heating exothermic reaction of mono comb-shaped siloxane polymer electrolyte starts at approximately 300 °C. Comparison of the heat generation profiles from ARC tests indicates that SPE reduces the intensity of exothermic reactions resulting from charged electrodes and electrolyte.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1b5fda34967c676372b5509d6f162ff6 https://doi.org/10.1016/s0013-4686(03)00207-x Zobrazit plný text záznamu Full Text from ScienceDirect