| Autor: |
Hari Gunasingham, B. T. Tay, K. P. Ang |
| Rok vydání: |
1985 |
| Předmět: |
|
| Zdroj: |
Analytica Chimica Acta. 176:143-150 |
| ISSN: |
0003-2670 |
| DOI: |
10.1016/s0003-2670(00)81641-4 |
| Popis: |
The electrolytic efficiency of the wall-jet detector in normal-phase high-performance liquid chromatography (between 0.1 and 5%) is significantly less than its efficiency in reversed-phase separations. A large-volume wall-jet cel with a Ag/Ag+ reference serves as the detector system in evaluating the effects of various chromatographic conditions on efficiency. Anthraquinone, phenanthrenaquinone (both at 10-3–10-4 M) and three estrogen gen steroids (at 10-2–10-3 M) are used as samples with ethanol/ hexane eluents. The effect of pH depends on the sample; increased ethanol concentrations and lower flow rates improve the efficiency. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
