The impact of natural and artificial weathering on the visual, colour and structural changes of seven tropical woods
Autor: | Miloš Pánek, Miroslava Mamoňová, Ladislav Reinprecht, František Kačík |
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Rok vydání: | 2017 |
Předmět: |
040101 forestry
0106 biological sciences Thinning Chemistry Mineralogy Forestry Weathering 04 agricultural and veterinary sciences 01 natural sciences Bluing Ground contact chemistry.chemical_compound Greening 010608 biotechnology Environmental chemistry 0401 agriculture forestry and fisheries Lignin General Materials Science sense organs Cellulose crystallinity |
Zdroj: | European Journal of Wood and Wood Products. 76:175-190 |
ISSN: | 1436-736X 0018-3768 |
DOI: | 10.1007/s00107-017-1228-1 |
Popis: | This study investigates the effects of wood weathering on changes in its macroscopic and colour characteristics in connection with changes in its molecular and anatomical structure. Seven hardwoods suitable for outdoor architecture—bangkirai, cumaru, cumaru rosa, ipe, jatoba, kusia, and massaranduba—were exposed to the exterior out of ground contact for 1–36 months according to EN 927-3, and for 1–12 weeks in Xenotest with water spraying according to partly modified EN 927-6. With prolonged weathering, the following changes occurred in the top surfaces of all tropical woods: (1) visual—creation of longitudinal macro-cracks, (2) spectrophotometry and CIE-L ∗ a ∗ b ∗ —darkening in exterior exposure mainly due to pollutants, except for ipe, and vice versa lightening in Xenotest, as well as greening and blueing in both modes of exposure, (3) FTIR—faster decrease of guaiacyl than syringyl lignin, absolute decrease of conjugated and unconjugated carbonyl groups in the newly formed lignin-polysaccharide-extractive substrate in the photo-oxidized and washed-out cell walls, and decrease of cellulose crystallinity, (4) SEM—damaging of cell-walls by micro-cracks, and their degradation by thinning. Connections between changes of the individual characteristics of weathered woods, for example, between the colour (ΔE*, etc.) and the molecular structure (carbonyls, etc.), were also determined. |
Databáze: | OpenAIRE |
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