Thermodynamic Database of the Phase Diagrams in the Sc-X Binary Systems
| Autor: | Shu Liang Wang, Jia Lian Li, Yuanhua Lin, Xingjun Liu, Xue Qin, L. J. Zhou, Yu Heng Li |
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| Rok vydání: | 2016 |
| Předmět: |
010302 applied physics
Work (thermodynamics) Materials science Mechanical Engineering Weldability Alloy Intermetallic Thermodynamics 02 engineering and technology engineering.material 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Gibbs free energy symbols.namesake Mechanics of Materials Phase (matter) 0103 physical sciences symbols engineering General Materials Science 0210 nano-technology CALPHAD Phase diagram |
| Zdroj: | Materials Science Forum. 850:439-443 |
| ISSN: | 1662-9752 |
| DOI: | 10.4028/www.scientific.net/msf.850.439 |
| Popis: | Sc-based alloys have been used as aero-structures materials, and Sc addition on wrought alloys has positive effects on weldability and welding properties. Phase diagrams play an effective role during the development of new type of alloy with good properties. Therefore, to establish the thermodynamic database of Sc-X binary systems is important and necessary.In the present work, the thermodynamic assessments of Sc-X (Ag, B, Cr, Er, Gd, Mo, Th, W, Y, Zr) binary systems was carried out by using CALPHAD (Calculation of Phase Diagrams) method based on the experimental data including thermodynamic properties and phase equilibria. The Gibbs free energies of the solution phases were described by the sub-regular solution model with the Redlich-Kister equation, and those of the intermetallic compounds were described by the sub-lattice model. A set of self-consistent thermodynamic parameters were derived for describing the Gibbs free energies of each solution phase and intermetallic compound. The calculated phase diagrams and thermodynamic properties are in good agreement with experimental data. The thermodynamic database of the Sc-X (Al, Ag, B, Ca, Co, Cr, Cu, Er, Fe, Ga, Gd, Ge, La, Li, Mg, Mn, Mo, Ni, Pb, Pd, Ru, Sn, Th, W, Y, Zn, Zr) binary systems have been developed, which can provide much important thermodynamic information for multicomponent Al-Sc based alloys. |
| Databáze: | OpenAIRE |
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