Autor:	Herman van Bekkum, Boudewijn J. Zuurdeeg, Jurg Bremmer, R.S. Downing, Jan C. van der Waal, P.J. Kunkeler
Rok vydání:	1998
Předmět:	chemistry.chemical_classification Oxide chemistry.chemical_element General Chemistry Heterogeneous catalysis Aldehyde Catalysis chemistry.chemical_compound chemistry Organic chemistry Lewis acids and bases Zeolite Selectivity Titanium
Zdroj:	Catalysis Letters. 53:135-138
ISSN:	1011-372X
DOI:	10.1023/a:1019049704709
Popis:	Zeolite titanium Beta is found to be an effective catalyst for the industrially relevant rearrangement of α-pinene oxide to campholenic aldehyde, giving selectivities of up to 89% in the liquid phase. In the gas phase, up to 94% selectivity is obtained at conversions above 95%, which exceeds the best values obtained with homogeneous Lewis acid catalysts. The selectivity obtained is profoundly influenced by the solvent or co‐adsorbate applied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1b2238f172ef4d8f92eb92b3000f6763 https://doi.org/10.1023/a:1019049704709 Zobrazit plný text záznamu Full text from SpringerLink