1,3-Diisonitrosoacetone and 4, 4l-Bis (Diethylamino) Benzophenone Oxime as Methanesulfonyl Chloride Vapor-Sensing Coatings for Optical Based Microsensors
| Autor: | Vikki D. Henderson, Thaddeus J. Novak, John A. Parsons |
|---|---|
| Rok vydání: | 1990 |
| Předmět: |
Methanesulfonyl chloride
Silica gel Chromogenic Biochemistry (medical) Clinical Biochemistry Oxime Biochemistry Chloride Analytical Chemistry chemistry.chemical_compound chemistry Reagent Electrochemistry Benzophenone medicine Organic chemistry Gas detector Spectroscopy medicine.drug Nuclear chemistry |
| Zdroj: | Analytical Letters. 23:169-182 |
| ISSN: | 1532-236X 0003-2719 |
| Popis: | The chromogenic detector reagents 1, 3-diisonitrosoacetone (DIA) and 4, 4l-bis (diethylamino)benzophenone oxime (EMKO) have been studied as solid-state coatings for sensing methanesulfonyl chloride vapor. The strength of the optical detection signals produced on contact of the coatings with methanesulfonyl chloride vapor are strongly affected by the composition of the solid reaction support; silica is the preferred support for coatings made with either reagent. When monitored with a fiber-optic spectrophotorneter, coatings made with DIA and EMKO are capable of sensing rnethanesulfonyl chloride vapor down to the low pprn level. At 25°C the DIA coatings are stable for up to five days while the EMKO coatings are stable for less than one day. |
| Databáze: | OpenAIRE |
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