Synthesis and Characterization of the New Series of Chromium−Group 15 Hydride Complexes [Et4N]2[HE{Cr(CO)5}3] (E = As, Sb)

Autor:	Gene-Hsiang Lee, Shie-Ming Peng, Minghuey Shieh, Jiann Jang Cherng, Chuen Her Ueng
Rok vydání:	2000
Předmět:	Inorganic Chemistry Crystallography Chromium Character (mathematics) Series (mathematics) Group (periodic table) Hydride Chemistry Organic Chemistry Metallurgy chemistry.chemical_element Physical and Theoretical Chemistry Characterization (materials science)
Zdroj:	Organometallics. 19:213-215
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om990717z
Popis:	The new series of trigonal-pyramidal chromium complexes [HE{Cr(CO)5}3]2- (E = As (Ia), Sb (Ib)) were obtained from the reactions of E2O3 (E = As, Sb) with Cr(CO)6 in concentrated KOH methanolic solution. These are the first examples of group 6 complexes containing E−H fragments (E = As, Sb), and the hydrogens are shown to be more hydridic than those in the related iron complexes due to the more electropositive character of Cr.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1af3480bc7946a705a29c98f01c05ae4 https://doi.org/10.1021/om990717z Zobrazit plný text záznamu