Stereoselectivity of electroreduction of a menthone-isomenthone mixture

Autor:	E. I. Klabunovskii, N. D. Zubareva, A. A. Vedenyapin
Rok vydání:	2009
Předmět:	Electrode material General Chemical Engineering General Chemistry Menthone Cathode law.invention Solvent chemistry.chemical_compound chemistry law Electrode Organic chemistry Stereoselectivity Menthol
Zdroj:	Russian Journal of Applied Chemistry. 82:1234-1237
ISSN:	1608-3296 1070-4272
Popis:	Electroreduction of an equilibrium menthone-isomenthone mixture at a controlled potential in a diaphragm cell on various cathodes was studied. The influence exerted by the nature of a solvent and of an electrode, electrode material, and various additives on the reduction stereoselectivity of ketones was examined. Conditions for a predominant formation of the most stable of the four isomeric alcohols being formed, menthol, were found.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1adc000772cea49e7275d64a202a05c9 https://doi.org/10.1134/s1070427209070143 Zobrazit plný text záznamu Full text from SpringerLink