Heteroarylation of Ethers, Amides, and Alcohols with Light and O2

Autor:	Joyram Guin, Manotosh Bhakat, Promita Biswas, Jayanta Dey
Rok vydání:	2021
Předmět:	Chemistry Organic Chemistry Organic chemistry Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic Letters. 23:6886-6890
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.1c02440
Popis:	An efficient protocol for the Cα-H heteroarylation of ethers, amides, and alcohols using air and light under mild conditions is described. The reaction is applicable to a wide spectrum of functional groups. The generation of C-radicals via photoinduced aerobic oxidation of ethers, amides, and alcohols is the key feature of the process. Control experiments suggest a radical pathway for the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1ace0c30b11869659703b241193fdef1 https://doi.org/10.1021/acs.orglett.1c02440 Zobrazit plný text záznamu