Autor:	Nina I. Ivanova, A. M. Reutskaya, S. I. Shaikhutdinova, Svetlana N. Arbuzova, Boris A. Trofimov, Nina K. Gusarova
Rok vydání:	2003
Předmět:	Benzaldehyde Tris chemistry.chemical_compound chemistry Sodium Radical Oxide Organic chemistry chemistry.chemical_element General Chemistry Medicinal chemistry Phosphine
Zdroj:	Russian Journal of General Chemistry. 73:877-879
ISSN:	1070-3632
DOI:	10.1023/a:1026340532022
Popis:	Symmetrical and unsymmetrical tertiary phosphine oxides containing benzyl and 5-chloro-2-thienyl radicals stereoselectively react with benzaldehyde in the sodium amide-THF system to form the E isomers of 1-organyl-2-phenylethene and diorganylphosphinic acids in high yields. Triethyl, tris(2-phenyl- ethyl)-, and tris[(4-methoxyphenyl)methyl]phosphine oxides under the above-mentioned conditions do not react with benzaldehyde.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1ac0c22056b8733423f60f70b3cc31b9 https://doi.org/10.1023/a:1026340532022 Zobrazit plný text záznamu Plný text ve formátu PDF