Impurities detection by optical techniques in KH 2 PO 4 crystals

Autor: Fabien Pilon, Bertrand Bertussi, Jean-Claude Birolleau, Matthieu Pommiès, Audrey Surmin, David Damiani, Christophe Dujardin, Xavier Le Borgne, Hervé Piombini
Rok vydání: 2006
Předmět:
Zdroj: SPIE Proceedings.
ISSN: 0277-786X
DOI: 10.1117/12.695323
Popis: In this paper we examine how optical techniques can be used for impurities and defects detection in KH 2 PO 4 (KDP) components. This is important in so far as some of these defects are responsible for a weaker than expected laser-induced threshold in these materials. Photothermal deflection, polariscopy, fluorescence and photoexcitation are investigated with the aim of localizing and identifying the laser-induced damage precursors. Impurities concentration is measured directly by ICP-AES and Fe is accordingly checked to be at the origin of a higher absorption in the prismatic sectors of rapidly grown KDP crystals. We also exhibit a fluorescence signal in the near-ultraviolet range by pumping at 248 nm; in rapidly grown crystals, in the same way as iron, the incorporation rate of the fluorescent centers is shown to depend on the growth sector.
Databáze: OpenAIRE