Thermodynamic Study of Monoligand and Protonated Complexes of Copper(II) with Triglycine in Aqueous Solutions

Autor:	G. G. Gorboletova, A. A. Metlin
Rok vydání:	2018
Předmět:	Aqueous solution Materials science 010405 organic chemistry Enthalpy chemistry.chemical_element Protonation Direct calorimetry 010402 general chemistry 01 natural sciences Copper 0104 chemical sciences chemistry Ionic strength Thermal Physical chemistry Physical and Theoretical Chemistry
Zdroj:	Russian Journal of Physical Chemistry A. 92:2169-2175
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s0036024418110110
Popis:	The thermal effects of the interaction between triglycine solutions and Cu(NO3)2 solutions at 298.15 K with ionic strength from 0.2 to 1.0 (KNO3) are measured via direct calorimetry. The enthalpies of CuL+, CuHL2+, CuHL $$_{2}^{ + }$$ , CuH2L $$_{2}^{{2 + }}$$ complexation are determined. A complete thermodynamic description of complexation processes is obtained. Based on an analysis of the thermodynamic parameters and the results from spectrophotometric measurements, conclusions are drawn regarding the structure of the investigated complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1a5b7da6f38af761cbd4c3117bccd71c https://doi.org/10.1134/s0036024418110110 Zobrazit plný text záznamu Full text from SpringerLink