A novel glycoside anomerization catalyzed by trimethylsilyl bromide and zinc bromide in combination

Autor: Kunio Higashi, Emiko Shioya, Kouichi Uoto, Kiyoshi Nakayama, Tsuneo Kusama
Rok vydání: 1991
Předmět:
Zdroj: Chemical and Pharmaceutical Bulletin. 39:590-592
ISSN: 1347-5223
0009-2363
Popis: A novel glycoside anomerization occurred when trimethylsilyl bromide (TMSBr) and zinc bromide were utilized in combination as a catalyst. Treatment of β-glycosides with TMSBr and zinc bromide in the presence of alcohols afforded anomerized products in good yields.
Databáze: OpenAIRE