Directed metalation reactions 2-position of methoxy- and chloroferrocene

Autor:	B. P. Koonsvitsky, Donald W. Slocum, C. R. Ernst
Rok vydání:	1972
Předmět:	Inorganic Chemistry chemistry.chemical_compound Ferrocene chemistry Metalation Position (vector) Organic Chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Biochemistry Medicinal chemistry
Zdroj:	Journal of Organometallic Chemistry. 38:125-132
ISSN:	0022-328X
Popis:	Unequivocal demonstration that the position of lithiation of chloro- and methoxyferrocene is the 2-position is provided. 2-Methylchloroferrocene and 2-(methoxymethyl)methoxyferrocene were prepared from the respective 2-lithio intermediates. These derivatives were shown to be identical to samples of these compounds prepared by the lithiation of [(dimethylamino)methyl]ferrocene, a procedure well documented to produce 1,2-disubstituted ferrocenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1a52ba51fd615a6380b5c363487809dc https://doi.org/10.1016/s0022-328x(00)81369-8 Zobrazit plný text záznamu