Enantioselective total synthesis of streptazolin. The tandem use of iminium ion vinylsilane cyclizations and intramolecular acylations

Autor:	Christopher J. Flann, Larry E. Overman
Rok vydání:	1987
Předmět:	Intramolecular reaction Stereochemistry Enantioselective synthesis Iminium Total synthesis General Chemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Intramolecular force Stereoselectivity Vinylsilane Streptazolin
Zdroj:	Journal of the American Chemical Society. 109:6115-6118
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00254a034
Popis:	Synthese a partir de bromo-4 trimethylsilyl-4 butene-3ylamine (=R-NH 2 ) et de dimethoxy-3,4 perhydro furannedione-2,5 via la cyclisation de R-1 dimethoxy-3,4 oxo-5 pyrroline-1ium et l'acylation de l'α,β-dimethoxy ethoxycarbonyl-1 tetrahydro-1,2,5,6 pyridinepropionate-2 d'ethyle
Databáze:	OpenAIRE
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