Electrocatalysis over Pd catalysts: A very efficient alternative to catalytic hydrogenation of cyclohexanone

Autor:	Ciprian M. Cirtiu, Hugues Ménard, Anne Brisach-Wittmeyer
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Acetic acid Aqueous solution chemistry Supporting electrolyte Inorganic chemistry Cyclohexanol Cyclohexanone Physical and Theoretical Chemistry Heterogeneous catalysis Electrocatalyst Catalysis
Zdroj:	Journal of Catalysis. 245:191-197
ISSN:	0021-9517
DOI:	10.1016/j.jcat.2006.10.010
Popis:	Electrocatalytic reaction was examined as an alternative method for the catalytic hydrogenation of cyclohexanone over Pd catalysts. The behavior of Pd/alumina catalyst and finely divided Pd catalyst in the electrocatalytic and catalytic hydrogenation of cyclohexanone in aqueous solution were investigated as a comparative study. The role of the pH of the solution was studied both in electrocatalytic and catalytic hydrogenation over Pd/alumina catalyst using acetic acid as a supporting electrolyte. High current yields were obtained for the electrocatalytic process, whereas, as expected from the literature, the catalytic hydrogenation was inefficient.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::19fc02057a37dd6fd0c8ddf43937084e https://doi.org/10.1016/j.jcat.2006.10.010 Zobrazit plný text záznamu Full Text from ScienceDirect