ChemInform Abstract: Stereo- and Chemodivergent NHC-Promoted Functionalisation of Arylalkylketenes with Chloral

Autor:	Andrew D. Smith, Alexandra M. Z. Slawin, Gwydion Churchill, David J. Fox, James Douglas
Rok vydání:	2016
Předmět:	chemistry.chemical_compound Chemistry Organocatalysis Enantioselective synthesis Organic chemistry Chloral General Medicine
Zdroj:	ChemInform. 47
ISSN:	0931-7597
DOI:	10.1002/chin.201616118
Popis:	Stereo- and chemodivergent enantioselective reaction pathways are observed upon treatment of alkylarylketenes and trichloroacetaldehyde (chloral) with N-heterocyclic carbenes, giving selectively either β-lactones or α-chloro esters.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::19fb7a5e9245d51a879a89bf56c822d3 https://doi.org/10.1002/chin.201616118 Zobrazit plný text záznamu Plný text