Sterically encumbered hexakis(alkylseleno)benzenes: conformational behavior of hexakis(iso-propylselenomethyl)benzene toward Hg2+ ions on selective recognition

Autor:	Ray J. Butcher, Shabana Khan, Monika Maheshwari, Jai Deo Singh
Rok vydání:	2008
Předmět:	Steric effects chemistry.chemical_compound Molecular recognition chemistry Stereochemistry Organic Chemistry Drug Discovery Benzene Biochemistry Ion
Zdroj:	Tetrahedron Letters. 49:117-121
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2007.11.007
Popis:	An efficient synthesis and structural aspects of a novel class of hexakis(alkylseleno)benzenes [(RSeCH 2 ) 6 C 6 ] (R = Me, i Pr, n Bu, s Bu, t Bu, n Pn, n Hx, n Oct, 1-methylnaphthalene) by the reaction of hexakis(bromomethyl)benzene with RSe − ions is demonstrated. Preliminary data on ion-sensing properties reveal that these species may act as selective ionophores for Hg 2+ ions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::19e66e4825eeb7caacba8f2d8ec0f153 https://doi.org/10.1016/j.tetlet.2007.11.007 Zobrazit plný text záznamu Full Text from ScienceDirect