SYSTHESIS AND OPTICAL PROPERTIES OF RARE EARTHS DOPED NANO-SEMICONDUCTORS AND THEIR APPLICATIONS
Autor: | Shuji Komuro, Susumu Harako, Xinwei Zhao, Shinri Noguchi |
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Rok vydání: | 2002 |
Předmět: | |
Zdroj: | International Journal of Modern Physics B. 16:4294-4301 |
ISSN: | 1793-6578 0217-9792 |
DOI: | 10.1142/s0217979202015297 |
Popis: | Er and Yb have been doped into nanocrystalline Si and ZnO thin films. Sharp and intense photoluminescence (PL) lines related to intra-4f transitions in the rare earth ions were observed. The optical transition dynamics of the rare earth ions were investigated by time-resolved PL measurements. It was demonstrated that a nano-meter sizing of Si widened the energy bandgap and led to an increase of doping densities of the rare earths. It was also shown that the Er-related PL gave rise to different features under direct and indirect excitations indicating a strong interaction of electron-hole pairs in the host with 4f electrons in the rare earth ions. A co-doping effect of Yb and Er into nanocrystalline Si was presented also. Our results suggested a rare earth-rare earth coupling between the Yb 3+ ions and the Er 3+ ions, which transferred the energy from Yb to Er and enhanced the 1.54 μm PL of Er. |
Databáze: | OpenAIRE |
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