SYNTHESIS AND C-S BOND FISSION OF 1,3-DIARYL-3-THIOGLYCOLIC ACID-1-PROPANONES

Autor:	Mohamed E. Elba
Rok vydání:	2000
Předmět:	Chalcone Reaction mechanism Ethanol Fission Organic Chemistry Biochemistry Inorganic Chemistry NMR spectra database chemistry.chemical_compound chemistry Elemental analysis Polymer chemistry Organic chemistry Thioglycolic acid
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 160:233-240
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426500008043683
Popis:	1,3-Diaryl-3-thioglycolic acid-1-propanones 3a-k have been synthesized by the reaction of either erythro-2,3-dibromo-1,3-diaryl-1-propanones 1a-k or their corresponding trans-chalcones 2a.k with disodio-thioglycotate in absolute ethanol. The structure of the products was proven by UV, IR, NMR spectra and elemental analysis. A reaction mechanism leading to the products, and the carbon-sulfur bond fission in alkaline medium were discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::19d0b7005a822488b2673391d38e93cb https://doi.org/10.1080/10426500008043683 Zobrazit plný text záznamu