Three-component Heck–Diels–Alder cascade processes involving alkylallenes, aryl iodides and dienophiles

Autor:	Michael D. Uttley, Ronald Grigg, Visuvanathar Sridharan, Stewart R. Korn, Joanne Hinsley, Stephen Brown
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Chemistry Heck reaction Aryl fungi Organic Chemistry Drug Discovery Diels alder Organic chemistry Biochemistry Adduct
Zdroj:	Tetrahedron. 57:10347-10355
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)01062-6
Popis:	A wide variety of aryl/heteroaryl iodides undergo an intermolecular Heck reaction with alkylallenes to furnish 1,3-dienes. These subsequently react in situ with various dienophiles to give Diels–Alder adducts. The chemistry has been extended to incorporate cyclisation-anion capture methodology and the stereochemistry of the products has been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::19c847402e85625dec97eaf213c92798 https://doi.org/10.1016/s0040-4020(01)01062-6 Zobrazit plný text záznamu Full Text from ScienceDirect