ChemInform Abstract: A Novel Reaction of Acetanilide with Nitrobenzene in DMSO. An Unusual Solvent Assisted Regioselective Aromatic Nucleophilic Substitution

Autor:	Nagaraj R. Ayyangar, S. N. Naik, K. V. Srinivasan
Rok vydání:	2010
Předmět:	Solvent Nitrobenzene chemistry.chemical_classification chemistry.chemical_compound chemistry Base (chemistry) Nucleophilic substitution Regioselectivity Organic chemistry General Medicine Solvent effects Medicinal chemistry Acetanilide
Zdroj:	ChemInform. 22
ISSN:	0931-7597
DOI:	10.1002/chin.199126147
Popis:	The reaction of acetanilide (1) with nitrobenzene (2) in the presence of a base in DMSO yielded p -nitrosodiphenylamine (3) as the major product. This unusual regioselective formation of the deoxygenated product 3 has been rationalized in terms of solvent effects exerted by DMSO.
Databáze:	OpenAIRE
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