1,1- Bis(diphenylphosphinoyl)ethanol. Synthesis and complexes with neodymium and copper nitrates
Autor: | E. I. Matrosov, D. I. Lobanov, M. I. Kabachnik, Tatyana A. Mastryukova |
---|---|
Rok vydání: | 1994 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 43:874-877 |
ISSN: | 1573-9171 1066-5285 |
Popis: | A preparative method for the synthesis of 1,1-bis(diphenylphosphinoyl)ethanol (1) has been elaborated. In CHCl3 and MeCN solutions compound1 is associated into H-bonded dimers (-ΔH ≈ 12 kcal mol−1). Complexes of compound1 with NdIII, CuII, and CuI nitrates have been studed. The H-bonded dimers are retained upon complexing. |
Databáze: | OpenAIRE |
Externí odkaz: |