1,1- Bis(diphenylphosphinoyl)ethanol. Synthesis and complexes with neodymium and copper nitrates

Autor: E. I. Matrosov, D. I. Lobanov, M. I. Kabachnik, Tatyana A. Mastryukova
Rok vydání: 1994
Předmět:
Zdroj: Russian Chemical Bulletin. 43:874-877
ISSN: 1573-9171
1066-5285
Popis: A preparative method for the synthesis of 1,1-bis(diphenylphosphinoyl)ethanol (1) has been elaborated. In CHCl3 and MeCN solutions compound1 is associated into H-bonded dimers (-ΔH ≈ 12 kcal mol−1). Complexes of compound1 with NdIII, CuII, and CuI nitrates have been studed. The H-bonded dimers are retained upon complexing.
Databáze: OpenAIRE