New Chalcogenide Cobalt Complexes with Diimine Ligands: Synthesis and Crystal Structure
| Autor: | Taisiya S. Sukhikh, Sergei N. Konchenko, A. Yu. Konokhova, M. Yu. Afonin |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Chalcogenide chemistry.chemical_element NacNac Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Tellurium Single crystal Cobalt Diimine Selenium |
| Zdroj: | Journal of Structural Chemistry. 60:1463-1467 |
| ISSN: | 1573-8779 0022-4766 |
| Popis: | Reactions of a low-valent cobalt complex [Co(nacnac)(η6-C7H8)] (1) ((nacnac)− = (HC(C(Me)NC6H3-iPr2)2)−) with selenium and tellurium are studied. Two new binuclear complexes [(Co(nacnac))2(μ,η2-Se2)] (2) and [(Co(nacnac))2(μ,η2-Te2)] (3) have been isolated and characterized. The structures of the complexes are determined by single crystal X-ray diffraction. |
| Databáze: | OpenAIRE |
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