CO dissociation activities of clean Pt {430}, {320}, {520}, {310}, {410} and {210}: a comparison with the predictions of Banholzer's orbital symmetry model

Autor:	Ralf Vanselow
Rok vydání:	1991
Předmět:	Stereochemistry Thermodynamics chemistry.chemical_element General Chemistry Catalysis Dissociation (chemistry) Monod-Wyman-Changeux model chemistry.chemical_compound Adsorption chemistry Atomic orbital Platinum Organometallic chemistry Carbon monoxide
Zdroj:	Catalysis Letters. 10:19-26
ISSN:	1572-879X 1011-372X
DOI:	10.1007/bf00764732
Popis:	Banholzer et al. used an orbital symmetry model to predict the activity of various Pt faces for the dissociation of adsorbed NO. The predictions were later extended to the adsorption system CO/Pt. Our experimentally observed activities for the dissociation of CO on clean Pt {430}, {320}, {520}, {310}, {410} and {210} do not follow these predictions. However, the measured activities agree well with the predictions of the C6 “atomic site” model.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1984b2725139157343905fc7c3d9f9ea https://doi.org/10.1007/bf00764732 Zobrazit plný text záznamu Full text from SpringerLink