Synthesis and Crystal Structure of Binuclear Ruthenium Nitride Complex with Lithium Counter Cations as a Precatalyst of Water Oxidation Reaction in Artificial Photosynthesis
| Autor: | V. V. Dobrygin, L. V. Avdeeva, V. Yu. Tkachenko, Gennady V. Shilov, Z. M. Dzhabieva, T. S. Dzhabiev |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Materials Science (miscellaneous) chemistry.chemical_element Crystal structure Nitride Triclinic crystal system 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Redox 0104 chemical sciences Ruthenium Artificial photosynthesis Catalysis Inorganic Chemistry Crystallography chemistry Lithium Physical and Theoretical Chemistry |
| Zdroj: | Russian Journal of Inorganic Chemistry. 66:354-360 |
| ISSN: | 1531-8613 0036-0236 |
| DOI: | 10.1134/s0036023621030189 |
| Popis: | Lithium salt of binuclear ruthenium nitride complex Li3[Ru2NCl8 · 2H2O] has been synthesized. Structure of the complex was studied by X-ray diffraction. Triclinic crystals, space group P $$\bar {1},$$ a = 7.4044 A, b = 8.1818 A, c = 8.7123 A, α = 117.970°, β = 115.139°, γ = 90.014°, V = 408.65 A3, Z = 1, ρcalcd = 2.654 g/cm3. The complex is thermally stable, it dimerizes in acid medium to give tetranuclear cluster $${\text{R}}{{{\text{u}}}_{{\text{4}}}}{{{\text{N}}}_{{\text{2}}}}{\text{O}}_{{\text{5}}}^{ + }$$ , an active catalyst of four-electron oxidation of water to form O2. Catalyst efficiency in the reaction of water oxidation (TON) reaches 356 over 1 h. |
| Databáze: | OpenAIRE |
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