Density dependence of the conduction-band minimum in fluid krypton and xenon from field ionization of (CH3)2S

Autor:	K. N. Altmann, R. Reininger
Rok vydání:	1997
Předmět:	Chemical ionization Chemistry Krypton General Physics and Astronomy chemistry.chemical_element Ion Atmospheric-pressure laser ionization Xenon Ionization Field desorption Physics::Atomic and Molecular Clusters Physical and Theoretical Chemistry Atomic physics Electron ionization
Zdroj:	The Journal of Chemical Physics. 107:1759-1764
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.474529
Popis:	The ionization potential distribution of (CH3)2S doped in fluid krypton and xenon has been determined by means of field ionization in wide density ranges. These distributions are simulated by convoluting the field spectrum of pure (CH3)2S with the calculated polarization energy distribution of the dopant ion in the media. The density dependence of the conduction-band energy of excess electrons (V0) in the fluids is obtained from the energy shift between the experimental and simulated spectra. The resulting V0 values are compared with previous experimental results and several theoretical calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::19645815c528d8ad54f1ed2a0f276841 https://doi.org/10.1063/1.474529 Zobrazit plný text záznamu