Relative kinetics of the radical addition of benzyl bromide to unsaturated compounds

Autor:	S. I. Gapusenko, A. B. Terent'ev, S. V. Vitt, T. T. Vasil'eva
Rok vydání:	1992
Předmět:	Kinetics General Chemistry Benzoyl peroxide Photochemistry Medicinal chemistry Iron pentacarbonyl chemistry.chemical_compound Monomer Reaction rate constant Benzyl bromide chemistry Nucleophile Automotive Engineering medicine Dimethylformamide medicine.drug
Zdroj:	Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1567-1571
ISSN:	1573-9171 1063-5211
DOI:	10.1007/bf00863574
Popis:	The relative rate constants of the addition of the C6H5CH2 radical to unsaturated compounds CH2=CHX (X = C4H9, SiMe3, CF3, CO2Me, CN) were determined under the conditions of initiation by the Fe(CO)5 + DMF system or by benzoyl peroxide. Depending on the values of the relative addition rate constants, the monomers can be arranged into the following series (X): CF3≈C4H9
Databáze:	OpenAIRE
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