[3+2] Cycloaddition reactions of 1-substituted 3,3,3-trifluoropropenes with isonitriles – synthesis of pyrroles and pyrrolines

Autor:	Vadim M. Timoshenko, Yuriy G. Shermolovich, Yuriy N. Markitanov, Eduard B. Rusanov
Rok vydání:	2021
Předmět:	Sulfonyl chemistry.chemical_classification Trifluoromethyl 010405 organic chemistry Organic Chemistry Substituent 010402 general chemistry 01 natural sciences Medicinal chemistry Cycloaddition 0104 chemical sciences chemistry.chemical_compound chemistry Tosylmethyl isocyanide Sulfamide
Zdroj:	Chemistry of Heterocyclic Compounds. 57:253-260
ISSN:	1573-8353 0009-3122
DOI:	10.1007/s10593-021-02901-x
Popis:	Cycloaddition reactions of 3,3,3-trifluoropropene derivatives containing an alkoxycarbonyl, sulfonyl, sulfoximine, or sulfamide substituent in position 1 with ethyl isocyanoacetate proceed with the formation of 3-(trifluoromethyl)-2,3-dihydro-1H-pyrroles, whereas their reactions with tosylmethyl isocyanide lead to the formation of 4-(trifluoromethyl)-1H-pyrroles.
Databáze:	OpenAIRE
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