Field-Induced Behavior in a Liquid Formed by Achiral Banana-Shaped Molecules in the Vicinity of the Phase Transition Isotropic - B 2 Phase

Autor: J. Pavel, Huu Tinh Nguyen, Valéry Bourny, Vladimir Lorman, B. Mettout
Rok vydání: 2002
Předmět:
Zdroj: Ferroelectrics. 276:127-133
ISSN: 1563-5112
0015-0193
DOI: 10.1080/00150190214418
Popis: We have experimentally investigated the electric-field effect on the Isotropic - B 2 phase transition of an achiral banana-shaped mesogen 1,3-phenyllene bis[4-(4-10-alkoxy-benoyloxy)phenyliminomethyl] ( C 11 compound) [1]. From microscopic observations under electric fields and measurements of the D-E hysteresis loops, the T (temperature) - E (electric field) phase diagram was established, in which a critical field is observed in the isotropic liquid. This field characterizes the first nucleation of a ferroelectric state noted B F induced by the electric field. The results are interpreted in the framework of a phenomenological model that describes the Isotropic - B 2 phase transition by the condensation of a vector wave directly from the isotropic liquid [2].
Databáze: OpenAIRE