FeBr3-catalyzed regioselective hydroxysulfenylation of N-allylsulfonamides with sulfonyl hydrazides

Autor:	Lin-Chuang Zheng, Yue-Ming Li, Lin Li, Zhong-Qi Xu, Lili Duan
Rok vydání:	2019
Předmět:	Sulfonyl chemistry.chemical_classification Double bond 010405 organic chemistry Organic Chemistry Regioselectivity 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Catalysis chemistry Drug Discovery Organic chemistry
Zdroj:	Tetrahedron. 75:643-651
ISSN:	0040-4020
DOI:	10.1016/j.tet.2018.12.044
Popis:	Regioselective hydroxysulfenylation of unactivated C C double bonds was reported. Using FeBr3-bpy as the catalyst, Na2S2O8 as the oxidant, and sulfonyl hydrazides as the sulfenyl sources, hydroxysulfenylation of unfunctionalized olefins proceeded readily, giving a variety of β-hydroxysulfides in moderate to good isolated yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::191d7314cf301d524d52757cadc0f31b https://doi.org/10.1016/j.tet.2018.12.044 Zobrazit plný text záznamu Full Text from ScienceDirect