Multiple-bit storage properties of porphyrin monolayers on SiO2

Autor:	Qiliang Li, Guru Mathur, Jonathan S. Lindsey, Veena Misra, Thomas A. Sorenson, Kannan Muthukumaran, Robert C. Tenent, Srivardhan Gowda, Shyam Surthi, Qian Zhao
Rok vydání:	2004
Předmět:	Electrolytic capacitor Supercapacitor Materials science Physics and Astronomy (miscellaneous) technology industry and agriculture Analytical chemistry Porphyrin Capacitance law.invention Capacitor chemistry.chemical_compound chemistry law Monolayer Cyclic voltammetry Silicon oxide
Zdroj:	Applied Physics Letters. 85:1829-1831
ISSN:	1077-3118 0003-6951
Popis:	Hybrid molecule-silicon capacitors have been fabricated by the self-assembly of a monolayer of porphyrin molecules on a silicon oxide surface. The porphyrin employed [5-(4-dihydroxyphosphorylphenyl)-10,15,20-trimesitylporphinatozinc(II)] attaches to silicon oxide via a phosphonate linkage. Cyclic voltammetry current and capacitance/conductance measurements have been used to characterize the capacitors. The presence of multiple distinct peaks in current density and capacitance/conductance measurements are associated with oxidation and reduction of the molecular monolayer. The charge-storage states of the capacitor indicate applicability for use in multiple-bit memory devices.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::191c82a55754b28682a12406220efd44 https://doi.org/10.1063/1.1782254 Zobrazit plný text záznamu