A bonding-reactivity relationship for (carbon dioxide)bis(tricyclohexylphosphine)nickel: a comparative solid-state-solution nuclear magnetic resonance study (phosphorus-31, carbon-13) as a diagnostic tool to determine the mode of bonding of carbon dioxide to a metal center
| Autor: | Michele Aresta, Eugenio Quaranta, Roberto Gobetto, Immacolata Tommasi |
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| Rok vydání: | 1992 |
| Předmět: |
Magic angle
Carbon-13 Inorganic chemistry chemistry.chemical_element Tricyclohexylphosphine Nuclear magnetic resonance spectroscopy Inorganic Chemistry Nickel chemistry.chemical_compound Nuclear magnetic resonance chemistry Transition metal Molecule Reactivity (chemistry) Physical and Theoretical Chemistry |
| Zdroj: | Inorganic Chemistry. 31:4286-4290 |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/ic00047a015 |
| Popis: | 31 P and 13 C nuclear magnetic resonance spectra in the solid state and in solution, at variable temperature, have been used for the first time to determine a direct correlation of the modes of bonding of CO 2 in Ni(PCy 3 ) 2 (CO 2 ) in the two states. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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