Solubility of aluminum lithium hydride in the systems LiAlH4-ether-benzene and LiAlH4-ether-toluene at 25�

Autor:	S. M. Arkhipov, V. I. Mikheeva, A. E. Pruntsev
Rok vydání:	1971
Předmět:	Inorganic chemistry chemistry.chemical_element Ether General Chemistry Toluene Isothermal process law.invention chemistry.chemical_compound chemistry Lithium hydride Aluminium law Solubility Crystallization Benzene
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 20:2652-2654
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00853644
Popis:	1. Employing the isothermal method at 25°, the crystallization regions of LiAlH4 and LiAlH4·(C2H5)2O in the systems LiAlH4-ether-benzene and LiAlH4-ether-toluene were established. 2. The composition of the saturated solution, corresponding to the crystallization of these phases, was respectively: 7.8% LiAlH4, 36.9% (C2H5)2O, 55.3% C6H6 and 9.1% LiAlH4, 33.8% (C2H5)2O, 57.1% C7H8. 3. The solubility of LiAlH4 in ether at 25° is 27.8%, in benzene it is less than 0.02%, and in toluene it is approximately 0.02%.
Databáze:	OpenAIRE
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