Characterization of Atomic Layer Deposited Ultrathin HfO2 Film as a Diffusion Barrier in Cu Metallization

Autor: Prodyut Majumder, Rajesh Katamreddy, Christos G. Takoudis
Rok vydání: 2007
Předmět:
Zdroj: MRS Proceedings. 990
ISSN: 1946-4274
0272-9172
DOI: 10.1557/proc-0990-b09-03
Popis: Thermally stable, amorphous HfO2 thin films deposited using atomic layer deposition have been studied as a diffusion barrier between Cu and the Si substrate. 4 nm thick as-deposited HfO2 films deposited on Si are characterized with X-ray photoelectron spectroscopy. Cu/HfO2/ samples are annealed at different temperatures, starting from 500 °C, in the presence of N2 atmosphere for 5 min and characterized using sheet resistance, X-ray diffraction and scanning electron microscopy. Ultrathin HfO2 films are found to be effective diffusion barrier between Cu and Si with a high failure temperature of about 750 °C.
Databáze: OpenAIRE