Improvement in performance of Si-based thin film solar cells with a nanocrystalline SiO2–TiO2 layer

Autor: Dong-Sing Wuu, Chung-Yuan Kung, Yang-Shih Lin, Yu-Xuan Huang, Shui-Yang Lien
Rok vydání: 2014
Předmět:
Zdroj: Thin Solid Films. 570:200-203
ISSN: 0040-6090
Popis: In this paper, titanium dioxide (TiO 2 ) solution with grain sizes of 1–5 nm is prepared by microwave hydrothermal synthesis, and then mixed with silicon dioxide (SiO 2 ) solution to yield different SiO 2 /TiO 2 ratios. The mixed solution is then sol–gel spin-coated on glass as an anti-reflecting and self-cleaning bi-functional layer. The experimental results show that the transmittance is optimized not only by minimizing the reflectance by reflective index matching at the glass/air interface, but also by improving the film/glass interface adhesion. Adding SiO 2 into TiO 2 in a weight ratio of 5 leads to the highest average transmittance of 93.6% which is 3% higher than that of glass. All of the SiO 2 –TiO 2 films exhibit a remarkable inherent hydrophilicity even when not illuminated by ultra-violet light. Using the optimized SiO 2 –TiO 2 film in a hydrogenated amorphous silicon/microcrystalline silicon tandem, solar cell increases its conversion efficiency by 5.2%. Two months of outdoor testing revealed that cells with the SiO 2 –TiO 2 film avoid 1.7% of the degradation loss that is caused by dust and dirt in the environment.
Databáze: OpenAIRE