Synthesis, Crystal Structure, and Bioactivity of Mixed-Ligand Complex Zn (HL) (Im) (H2O)

Autor:	Feng-Ying Chen, Shui-Yang He, Heng Xin Li, Ping Liu
Rok vydání:	2012
Předmět:	chemistry.chemical_classification Denticity Hydrogen bond Stereochemistry Intermolecular force Hydrazone Crystal structure Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Molecule Imidazole Turbidimetry Physical and Theoretical Chemistry
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 43:121-124
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533174.2012.680109
Popis:	The reaction of Zn(Ac)2·2H2O with N-(2-propionic acid)-salicyloyl hydrazone, a tridentate ligand (C10H10N2O4, H3L), and imidazole (C3H4N2), a monodentate ligand, in MeOH:H2O = 3:1 (V/V) yields [Zn(HL)(C3H4N2)(H2O)]. The crystal structure has been determined by X-ray diffraction. In the compound, it crystallizes with two independent molecules in the unit and the two molecules are linked by an intermolecular hydrogen bond and one short contact. Zn is five-coordinated by one tridentate hydrazone ligand, one imidazole, and one water molecule. The coordination polyhedron around Zn(II) described as a distorted square-pyramid. In addition, antibacterial activities of the complex against coliform were investigated by turbidimetry/spectrometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::18be8e50e3ee06c201a40a240b8769d5 https://doi.org/10.1080/15533174.2012.680109 Zobrazit plný text záznamu