Kinetics and Mechanism of Slurry Phase Air Oxidation of Benzyl Alcohol over Zirconium Vanadate Catalyst

Autor:	Shweta Kanungo Joshi, Rajendra Prasad, Neena Sohani, Savita Khare
Rok vydání:	2020
Předmět:	010405 organic chemistry Kinetics Alcohol General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Zirconium vanadate chemistry.chemical_compound Chemical engineering chemistry Phase (matter) Slurry Mechanism (sociology)
Zdroj:	Asian Journal of Chemistry. 33:108-112
ISSN:	0975-427X 0970-7077
DOI:	10.14233/ajchem.2021.22947
Popis:	The kinetics of slurry phase air oxidation of benzyl alcohol to benzaldehyde over zirconium vanadate catalyst is reported in this study. Initial rates for the formation of product were determined by varying the partial pressures of the reactants. The data collected were found to satisfy a rate law: R = [(k1PBk2Po)/(k1PB + k2Po)]. The study suggests that reaction follows a Mars-Van Krevelen type of redox mechanism.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::188e818029b567a79bf096a8d551667c https://doi.org/10.14233/ajchem.2021.22947 Zobrazit plný text záznamu